Sunday, 7 December 2014

"PCBs" - Polychlorinated Biphenyls

PCB Transformers - http://mrg.bz/wrBCzJ

           Have you ever seen one of these old transformers on a pole near your home? Can they be hazardous? Have you heard of PCBs but wanted to know more? Well you've come to the right place!
            Polychlorinated Biphenyls, or PCBs as they are commonly known, are man-made chemicals that have become well known due to the environmental affects caused by bioaccumulation, particularly in Lake Ontario (Glooschenko & Glooschenko, 1975, Oliver & Niimi, 1998). They did not exist in natural environments until they were first made in the 1900’s (Barbalace, 2003). So there off to a rough start.

           PCBs were used in many products prior to the 1960s because of the physical properties of the chemical, which include being: non-flammable, insulating, persistent, and chemically stable (United States Environmental Protection Agency, 2013). However in the early 1970s, the toxic properties of the chemicals were identified which resulted in the reclassification of PCBs to that of a widespread contaminant (Glooschenko & Glooschenko, 1975). Yikes! Following reclassification, landfills and disposal companies had to rethink their use of the chemicals due to greater cost and changes associated with new regulations and handling procedures (Province of Alberta, 1996). This change, and greater awareness of health concerns drove the commercial and consumer use of PCBs down drastically.

           PCBs bio-accumulate in the environment, meaning that once they are present they are very hard to remove. The effect of which is an accumulation of the chemical over time. An example of this seen in Lake Ontario, as the contamination of microscopic organisms in the lake led to the buildup of PCBs in larger bony fish, rendering them unfit for human consumption by Health Canada guidelines (Glooschenko & Glooschenko, 1975, Oliver & Niimi, 1998).

           PCBs are still in use today, particularly for industrial purposes such as transformers (see picture above), and in old commercial products such as light ballasts (United States Environmental Protection Agency, 2013). The case of PCBs should be viewed as a lesson to future generations that will undoubtedly utilize chemical compounds without knowing all of the potential consequences.


References:

Barbalace, R. C. (2003). The chemistry of polychlorinated biphenyls. Accessed on-line: http://EnvironmentalChemistry. com/yogi/chemistry/pcb. html. 

Glooschenko, V., & Glooschenko, W. (1975). Effect of polychlorinated biphenyl compounds on growth of Great Lakes phytoplankton. Canadian Journal of Botany, 53(7),  653-659.

Oliver, B. G., & Niimi, A. J. (1988). Trophodynamic analysis of polychlorinated biphenyl congeners and other chlorinated hydrocarbons in the Lake Ontario ecosystem. Environmental science & technology, 22(4), 388-397.

Province of Alberta. (1996). Waste Control Regulation. Retrieved October 22, 2014 from http://www.qp.alberta.ca/documents/Regs/1996_192.pdf 


United States Environmental Protection Agency. (2013). Polychlorinated Biphenyls (PCBs). Retrieved October 20, 2014 from http://www.epa.gov/wastes/hazard/tsd/pcbs/about.htm

How Dangerous is Mercury?

Dental amalgams have been around now for about 150 years(6). At first when these were created people did not mind much about these mercury-containing fillings. With more research and knowledge gained, individuals started to realize that these dental amalgams might be dangerous to the human body. An amalgam is basically a mixture of metals and dental amalgams are liquid mercury mixed with alloys of other chemicals such as silver and tin(6). Another name for mercury is quicksilver(4). Some of mercury’s properties that make it useful includes that it is a liquid at room temperature, expands and contracts with temperature, conducts electricity, amalgamates with other metals, and kills bacteria and fungi(2). Mercury is released as a vapour when cinnabar ore is crushed and heated; the vapour is then cooled, condensed, and collected(5). The harmful and toxic effects of mercury depend on several different factors. The form, dose, age of a person who is exposed, duration of the exposure, and the general health of a person are just a few to start off with(4).


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For people that are concerned with getting mercury in their fillings, there are alternatives available such as the composite resin and gold foil fillings. The composite resin fillings are the more common alternative to dental amalgams. These fillings can also be called “white” or “tooth-coloured” fillings(1). The advantage of the composite resin fillings is that they blend in with the colour of the surrounding teeth and a disadvantage is that they can be a bit less durable than the dental amalgams and you might need to get these ones replaced at a faster rate compared to the dental amalgams(1). The other less common alternative is the gold foil fillings. These are more advantageous because they are much more durable and stronger, but the disadvantage is that they do cost more and they are more visible as they are gold-coloured(1). Overall, the amount of mercury that is present in the dental amalgams is minimal and are not as dangerous as people think and there are alternatives available for people that are strictly against getting mercury-fillings. 

References:
  1. Alternatives to Dental Amalgams. (2014, June 6). Retrieved November 5, 2014, from http://www.fda.gov/MedicalDevices/ProductsandMedicalProcedures/DentalProducts/DentalAmalgam/ucm171108.htm
  2. Case, R., Thompson, D., Hedin, K., Edwards, J., & Sieg, K. (n.d.). Mercury All Around Us. Mercury Pollutant Minimization Program Guidance Manual For Municipalities, 1-3. Retrieved October 31, 2014, from http://dnr.wi.gov/topic/wastewater/documents/mercuryPMP.pdf
  3. Greene, S. (2004). Composite Fillings. Retrieved November 5, 2014, from http://www.qualitydentistry.com/dental/composite/composite.html
  4. Mercury. (2014, March 10). Retrieved November 1, 2014, from http://www.epa.gov/mercury/effects.htm
  5. Rank, J. (2014). Mercury. Retrieved October 30, 2014, from http://www.madehow.com/Volume-4/Mercury.html
  6. Schwenk, M., Klein, R., & Templeton, D. (2009). Immunological Effects of Mercury. Pure and Applied Chemistry, 81(1), 153-167. Retrieved October 30, 2014, from http://pac.iupac.org/publications/pac/pdf/2009/pdf/8101x0153.pdf

So what is the Deal with Isopropanol?

Have you ever used printer ink, air fresheners, pledge, nail polish, or hair color 1? Well if you have, chances are you have been in contact with the chemical isopropanol ! This chemical is a component in many household products and is a starting material to make many more 1. Lucky for you, this chemical has been determined not to be very toxic and is generally safe for daily use 2.

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However, this does not mean that you can use this chemical without any danger being present. Do not let anything with isopropanol near an open flame or high temperatures. If this chemical is exposed to heat, it will explode 3! This means that you should take some caution when cleaning your bathrooms and painting your nails to make sure that your chemicals are not near heat.

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Isopropanol is a part of many products, as it is easy to make and has some useful properties 2. The main reason that isopropanol is found in so many products is because of its disinfectant properties 2. There has been some controversies over the use of isopropanol in hand disinfectants, especially in hospitals. Some people have said that through using hand sanitizers we have caused some resistance to certain bacteria 4. An alternative to using these hand sanitizers is good old fashion soap and water 4. Another possible concern is with the use of chemicals in general within the home. If this is a concern, there are other alternatives to keeping a nice clean home. One method would be to use natural cleaners, such as vinegar and water or hydrogen peroxide and water 5.


References:
1-Isopropanol, 2014. Household Products Database. http://householdproducts.nlm.nih.gov/cgi-bin/household/brands?tbl=chem&id=22&query=Isopropanol&searchas=TblChemicals (accessed October 27, 2014)2- Isopropyl Alcohol. http://www.princeton.edu/~achaney/tmve/wiki100k/docs/Isopropyl_alcohol.html (accessed October 28, 2014)3-R.J. Lewis, SR. Isopropyl Alcohol. In Hazardous Chemicals Desk Reference; C. Hsu; T. Stedeford, Eds.; John Wiley and Sons, Inc: USA, 2002; pp 674-675.4-Hand Sanitizers. http://www.toxipedia.org/display/toxipedia/Hand+Sanitizers. (accessed October 28, 2014)
5-Alternative to Isopropyl Alcohol. http://www.ehow.com/facts_7511838_alternative-isopropyl-alcohol.html (accessed October 28, 2014)
6-Source: Milne, N. Dark Flame Nails. http://www.flickr.com/photos/borispumps/6117970330/in/photolist-ddJnrp-6MbVi1-bxhWNi-6UtcZB-aZ9moi-6Uk4cf-bN4EPT-dF7sen-bNLUJP-bAujFe-6EnMoW-cb8WVS-oaJEBL-otZnoc-ajCcr5-oaJERo-otZbGH-oseDwa-oqcHPf-otZbJB-c8PUsW-7yaesp-bvno6Z-aniQ9V-enbbcr-7kVmni-7NKNTv-732cnv-a3Ekvd-pBAnmk-7NKNai-7dVu2q-bFXRf4-9jBkvp-8zBoFn-9VrKYy-7fddV4-7bNetM-8LothF-8WisUt-7dVDG7-732cAn-9cskmM-akLkLk-6Uk4uy-pBAkQK-oaGNyR-iKSghe-oq9YgC-bAUof4/ (accessed December 7, 2012). Used  with permission.
7- Source: Judy.Clean it up. http://www.flickr.com/photos/47490514@N02/7561101232/in/photolist-cw9BYm-9iwofp-6U1XJM-aBXGxL-6c17hM-oLTA95-foxewo-mXcmt-5g9J5-gTp4Lm-anuSbE-9yA9Eo-kjA3oJ-7wzQ8g-njm94t-fbBApa-fbRRNq-fbBA8B-cYTh8Q-bQvynV-pxZa-kjA1Pm-ftFZgQ-fbBA3c-ga4iw8-fzSp42-rZPW2-5wx2r1-jxVeDd-cnMUEE-cnMVMd-px356M-5Y7Ytx-anuS3C-foxeCS-nNKFRG-dxM8C8-fov9XU-JW3h5-5GT3Bx-6kcA7G-ans3hv-ans3eR-anuSjG-anuS7W-ans36t-kjy4m8-nAxRhz-nAQW85-kjxzu. (accessed December 7, 2014). Used with permission.

Bispheonl A- Friend or Enemy?

Bispheonl A- Friend or Enemy?

Have you ever wondered how plastics have the ability to maintain durability and strength over such a long period of time? The answer is BPA, the key monomer used in the production of polycarbonate (PC) plastics and epoxy resins, found in the lining of canned foods. Polycarbonate plastics are often used in containers that store food and beverages, such as water bottles (1).
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BPA is used in a broad variety of consumer products such as sports equipment and medical devices(2).Bispheonl A, commonly referred to as BPA, is a carbon based  synthetic compound that belongs to the group of diphenylmethane derivatives and bisphenols(3).Its physical form is generally found in the appearance of crystals with a melting point of 160˚C (4). Chemists discovered BPA in 1891 (2), but it wasn’t until 1957 that BPA began to be used in certain plastics for commercial use (5&6).

If it was discovered decades ago, why did it take so long to hit the consumer market? The reason for this is because BPA was found to be an endocrine (or hormone) disrupting chemical. An endocrine disruptor is a substance which interferes with the production, secretion, transport, function and elimination of natural hormones (7).BPA in particular has the ability to mimic the hormone estrogen. Some major health concerns that can result from this include heart disease and a loss of connection between brain cells in primates, leading to potential problems with memory, learning and depression (7). This may result from BPA seeping into food and beverages from the containers that are made with BPA (5).  

Despite these negative impacts it is still being produced because it’s cheap, easy and efficient. The primary ingredients required are acetone and phenol generating an 80-95% yield of product (8).  The FDA has also announced that BPA is safe at very low levels that occur in some foods (5).

With such efficiency and FDA support, it is unlikely that BPA will disappear entirely. Using glass and porcelain containers instead of plastic containers for foods and liquids is a way of reducing BPA exposure. Limiting the number of canned goods consumed and switching to fresh produce is another easy alternative(5) 

References:

—  (1) "BISPHENOL A ALTERNATIVES IN THERMAL PAPER." United States Environmental Protection Agency (2014): 332-56. Web. 21 Nov. 2014. <http://www.epa.gov/dfe/pubs/projects/bpa/bpa-report-complete.pdf>
—  (2) BPA-Free Tips and Alternatives for Parents (n.d.). In baumhedlundlaw. Retrieved November 24, 2014, from http://www.baumhedlundlaw.com/bpa/bpa_safe.php
—  (3) Bisphenol A. (2014, November 25). In Wikipedia, The Free Encyclopedia. Retrieved 07:13, November 23, 2014, fromhttp://en.wikipedia.org/w/index.php?title=Bisphenol_A&oldid=635410677
—  (4) Haynes, W. (2012). 2,2-Bis(4-hydroxyphenyl)-propane. In D. R. Lide & T. J. Bruno (Eds.), CRC Handbook of Chemistry and Physics (93rd ed., pp. 3-56-3-57).
—  (5) Zeratsky, Katherine. "What is BPA, and what are the concerns about BPA?." mayoclinic. N.p., May 2013. Web. 21 Nov. 2014. <http://www.mayoclinic.org/healthy-living/nutrition-and-healthy-eating/expert-answers/bpa/faq-20058331>
—  (6) Bisphenol A (BPA): Use in Food Contact Application (2010, January). In FDA. Retrieved November 23, 2014, from http://www.fda.gov/NewsEvents/PublicHealthFocus/ucm064437.htm#understanding
—  (7) Nordqvist, C. (2014, September 26). What is BPA (bisphenol A)? Is BPA harmful?. In Medical News Today. Retrieved November 24, 2014, from http://www.medicalnewstoday.com/articles/221205.php
—  (8) Bisphenol A (n.d.). In PubChem. Retrieved November 24, 2014, from http://pubchem.ncbi.nlm.nih.gov/compound/Bisphenol_A#section=Top

(9)Products containing BPA. Picture taken by Alyssa Bawa. November 26, 2014.

Ethylene Oxide


Did you ever wonder how your bandages were sterilized? Think of it this way, your bandages are manufactured in some company and the workers are busy touching the bandages while they package them into boxes. Turns out Ethylene Oxide is used to prevent you from placing bacteria or other infectious agents on your open wounds. Ethylene Oxide is a 3 membered ring with the chemical formula: C2H4O, and can come in two forms gas (flammable) and liquid (below 15°F), (6). It has a sweet- ether like odor to it and is colorless at room temperature so it is often times hard to detect (6). Asides from being used to sterilize bandages it is useful in other disinfectants, detergents, intermediaries in other chemical reactions and has many other uses, (7). It gets its disinfecting properties by disrupting the DNA of bacterial microorganisms, stopping them from growing and multiplying on surfaces (2). It is produced by the oxidation of ethylene with air or oxygen (8). Ethylene Oxide is almost everywhere you go it is found in vents, and even automobile exhausts (3).
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This chemical can therefore have many routes of exposure to us, such as ingestion (the least common), inhalation, skin contact, and eye contact (1). Now this chemical seems like it does more good than harm but that’s not actually the case. It can cause symptoms such as headaches, dizziness, nausea, coma and even death (1). Most medical associations even classify Ethylene Oxide as a carcinogen because of its cancer-causing properties (1). Sadly this chemical was found in 15 batches of baby powder produced by the company Johnson & Johnson in India and got its license removed by the FDA (5). Shame on you Johnson & Johnson no one wants this carcinogen on their bottoms. If you want to still disinfect but avoid these horrible symptoms try using hydrogen peroxide, peracetic acid or even hypochlorite (4). These are all alternatives to Ethylene Oxide that are much safer and are also approved by the FDA (4).









References:

¡  (1) ARC, Specialty Products. (2013). Ethylene Oxide. Identification Of The Substance or Mixture And Of The Supplier. Retrieved from: http://www.balchem.com/sites/default/files/SDS_ARC_Ethylene%20Oxide_2013-04-01.pdf
¡  (2) Aspenberg, P., Lindqvist, S. (1998). Information Health Care, 69(2): 173-176. Ethene Oxide and bone induction. Retrieved from: http://informahealthcare.com/doi/pdf/10.3109/17453679809117622
¡  (3) EPA United States Environmental Protection Agency.(2000). Ethylene Oxide. Uses. Retrieved from:
¡  (4) HER, Health Care Environmental Resource Center. (n.d). Pollution Prevention and Compliance Assistance Information for the Healthcare Industry. Sterilants and Disinfectants in Healthcare Facilities. Retrieved from: http://www.hercenter.org/hazmat/steril.cfm#alternatives
¡  (5) Inoyri,R.(2013). International Business Times. Cancer-Causing Agent Found in Johnson & Johnson Baby Powders. Retrieved from: http://au.ibtimes.com/articles/463154/20130501/cosmetic-brand-johnson-license-cancer-causing-baby.htm#.VHVlCznBHzJ
¡   (6) (n.d.). Physical and Chemical Properties of Ethylene Oxide. Retrieved from: http://www.sbioinformatics.com/design_thesis/Ethylene_oxide/Ethylene-2520oxide_Properties&uses.pdf
¡  (7) RSC, Royal Society of Chemistry.(2014). Learning Chemistry. Ethylene Oxide. Retrieved from: http://www.rsc.org/learn-chemistry/resource/rws00006114/ethylene-oxide
  §  (9)Debt Free Through Spending.(2013). Retrieved November 25th, 2014, from: http://www.debtfreespending.com/super-cheap-band-aids-and-first-aid-kit-at-cvs-starting-62/